New or repaired water mains united states environmental. Advanced math handbook overview this handbook is designed for operators taking the class iii or class iv water operator certification exam. This tech briefprovides basic examples of these formulas and conversion factors. Protocols for the chlorination of drinking water humanitarian. Where v volume of water in the well m3 d diameter of the well m h depth of water m. Jul 10, 20 water chlorination is the process of adding the element chlorine to water as a method of water purification to make it fit for human consumption as drinking water. Chlorine that is added to water is consumed first to become combined chlorine before it can emerge as free chlorine. Bureau of safe drinking water, department of environmental protection. All potable water lines downstream from the water meter. A generic standard operating procedures for drinkingwater chlorination. Pounds 65% dry chlorine slope dry wt lbgal slope 5% sol pounds kilograms bleach 12. Alternative disinfectants and oxidants guidance manual.
Therefore, it is essential that enough sanitizer is maintained in water to kill microbes before they attach or become internalized in produce. If the water has a higher than normal chlorine demand such as waters with high iron, manganese, hydrogen sulfide or color, use the amount listed to achieve a 20 mgl dosage. As more water systems adopted the practice of chlorination, there was a corresponding decrease. Continuous chlorination of a private water supply can be done by various methods. In such circumstances, it is best to treat the water to reduce turbidity before chlorination. Water disinfection and the history of chlorination first continuous use in belgium 1902 to the purpose of aiding coagulation and making water biologically safe. To eliminate nh 3 in drinking water using the breakpoint process, e. First continuous use in america for municipal application to water was in 1908. Example calculations of chlorine dosage california water. The relative frequency and nature of these activities represent a potential contamination risk to water distribution systems if proper. Since the publication of this manual there have been significant developments both in terms of the technology and understanding of the disinfection of drinking water and in the supervisory role of the epa in the drinking water area. The fundamentals of chlorine chemistry and disinfection wi dnr.
Calculate the volume of water in the well using the formula. Chlorination is the most common form of disinfection and successfully controls many microorganisms. Abc formulaconversion table lets give it another try what is the area of a circle if the diameter is 40 feet. Cross out anything given that has nothing to do with solving the problem. If large amounts of chlorine are required, the overall cost of gas. This tool, in addition to the class iiiiv course manual, your operating experience and common sense, should help you pass the required certification exam. Calcium hypochlorite tablets are placed in each section of water lines as the lines are installed. The chlorine residual level can be accurately measured with a simple colour comparator device but as a rough guide the free residual level is at the top of the right range when chlorine becomes detectable. The chlorine is applied continuously and for a sufficient period to develop a solid column, or slug, of chlorinated water that will expose all interior surfaces to a concentration of about 100 mgl for at least 3 hours as it moves through the water main. The slug method of chlorination, which is used for large diameter water mains, consists of moving a column of highly concentrated chlorine water solution at least 300 mg. Principles and practices of drinkingwater chlorination. State water resources control board division of drinking water february 2018. Other methods allow for the determination of free chlorine, chloramines, other chlorine species, and total available chlorine, and are suitable for total chlorine concentrations up to 5 mglitre. Application points upsewer chlorination upsewer chlorination is the addition of chlorine to the wastewater before the wastewater reaches the treatment plant.
For more information about this procedure, please contact drinking water services dws shock chlorination is a procedure used whenever there is a need for emergency disinfection of tanks, wells and. The end of the distribution line used for water sampling. Although the collective research does not definitively show that dbps in drinking water cause adverse health effects in humans, high levels of these chemicals are undesirable. This information bulletin has been developed to provide information on the disinfection of water tanks with chlorine. In addition the ct concept allows the calculation of contact time. Drinking water chlorination world chlorine council. Basic water treatment math formulas for surface and well exams these formulas are intended to serve as a general resource and are not intended to be an all. Percent sodium hypochlorite %naocl is based on weight per volume wv in the equations below. Math for water treatment distribution wastewater treatment. Determine what is being requested with the correct units.
Disinfection equations for water pipes and storage tanks maine cdc drinking water program y 11 shs augusta, me 04330 y 2872070 y. In 1908, jersey city water works became the first system in the united states to practice largescale chlorination on a permanent basis. Disinfection with chlorine public water systems drinking. Typical levels of free chlorine or residual chlorine in drinking water are 0. Water chlorination is the process of adding chlorine or chlorine compounds such as sodium hypochlorite to water. You calculate that you will need 850 gallons of a 200 mgl solution to disinfect a water storage tank. Hypochlorite water chlorination gradually decreased in popularity, but it received renewed interest in 1928 with the commercial availability of hightest calcium hypochlorite, which was a more stable and active material than the various bleaching powders and. For a drinking water utility, chloramination may or may not be a good alternative to free chlorination. Chloramines are weaker oxidizing agents, and a higher disinfectant residual is required for similar results. Some dose pumps may be more manual in operation, where the pumps would be set to dose at.
Water research center chlorination of drinking water. Adding chlorine to water with ammonia in it does not act like you think it should. Often this work is performed by water utility employees as they are usually well acquainted with the use of chlorine. Chlorine is available as compressed elemental gas, sodium hypochlorite solution naocl or solid calcium hypochlorite caocl 2 1. This method is used to kill certain bacteria and other microbes in tap water as chlorine is highly toxic. Depending on the ph conditions required and the available storage options, different chlorinecontaining substances can be used. Measuring free or total chlorine in cooling water provides real time feedback signal for the chlorination system. Chlorine for water treatment is generally obtained and used as either liquefied chlorine gas or as sodium hypochlorite solution. In water, chlorine reacts to form hypochlorous acid and hypochlorites. The injection device should operate only when water is being pumped, and the water pump should shut off if the chlorinator fails or if the chlorine supply is depleted. The two chemical species formed by chlorine in water.
Enough chlorine must be provided to disinfect the water completely and to leave a free residual chlorine level in the water of 0. Chlorination can also be carried out using chlorinecontaining substances. Formulaconversion table for water treatment and water. State water resources control board division of drinking water february 2018 example calculations of chlorine dosage note. Epa 832f00022 september 2000 wastewater technology fact sheet dechlorination description dechlorination is the process of removing residual chlorine from disinfected wastewater prior to discharge into the environment. Amount of water in tank l concentration of chlorine required 1 mgl 2 mgl 5 mgl add ml add ml add ml 8 16 40 2000 16 32 80 5000 40 80 200 6000 48 96 240 7500 60 120 300.
The dosage formula is determined from the davidson pie, which is included. The chlorine that does not combine with other components in the water is free residual chlorine, and the breakpoint is the point at which free chlorine is available for continuous disinfection. Chlorination effectiveness is measured by the most probable number mpn of the indicator group, usually coliform bacteria e. Overview of chlorine chemistry in water treatment chlorination of public water supplies has been practiced for almost 100 years in the united states. Hsch chlorine granules or powder method calculate the volume of water in the well using the formula. These, are still disinfectants, but they are 40 to 60. Well disinfection can eliminate or reduce many different kinds harmful bacteria and viruses as well as harmless bacteria which can cause unpleasant taste and odors. Chlorination is the process of adding chlorine to drinking water to disinfect it and kill germs. Hypochlorite water chlorination gradually decreased in popularity, but it received renewed interest in 1928 with the commercial availability of hightest cal cium hypochlorite, which was a more stable and active material than the various. If a water system has been using free chlorination and switches to chloramination, the following points should be taken into account. Disinfection of mains should be accomplished only by workmen who have had experience with chlorine or other disinfecting agents.
The source water type and quality and the overall treatment process required to produce potable drinking water are primary factors to consider. Disinfection procedure for water distribution lines. Gas chlorination requires more sophisticated equipment and more training to apply safely. Chloramines are chemical compounds formed by chlorine combining with nitrogen containing contaminates in the pool water. The chlorine residual level can be accurately measured with a simple colour comparator device but as a rough guide the free residual level is at the top of the right range when chlorine becomes detectable in the water by taste or smell. Chlorine for water treatment is generally obtained and used as either liquefied chlorine gas or. Chlorine contact time calculations steps to solving a math problem. Calculating the chlorine dosage using method 2 200 mgl solution example. Chlorine destroys diseasecausing organisms in water and is the most commonlyused disinfectant in all regions of the world.
Chlorine concentration adjustment calculator for water. Electrochlorination is the process of producing hypochlorite by running an electric current through salt water. That is, all three produce hypochlorous acid, the oxidizing agent present for disinfection in water and waste water application. Water operator exam formula sheet 42008 1 foot 12 inches 1 minute 60 seconds cfs cubic feet per second 1 inch 2. Page 26 nsw health nsw private water supply guidelines 2. Percent sodium hypochlorite %naocl is based on weight per volume wv in the equations. When chloramines are used, the distribution system must be continually monitored for mono and dichloramine residuals and do. Adding chlorine as a hypochlorite is much simpler, requires less training and is safer. An ideal system supplies free chlorine at a concentration of 0. Different processes can be used to achieve safe levels of chlorine in drinking water. The three most common types of chlorine used in water treatment are. Water chlorination chloramination practices and principles.
Place one tablet in the test chamber a and add a few drops of the chlorinated water supply under test. The formula for determining contact times, alongside an example calculation. A typical schematic of a cooling water system is shown in figure 1. Introduction this procedure is to assist water system operators in shock chlorination and includes a shock chlorination calculation tool xls for disinfecting drinking water storage facilities. The killing effect of chlorine depends on the ph of the water, temperature, chlorine level and contact time i.
Supply water for disinfection and filling mains from temporary jumper with approved. For example, if water at the entry point to the distribution system has a free chlorine residual of 0. Amount of sodium hypochlorite for 10,000 gallons of water adjust the quantity to fit your tank size volumes are approximate and have been rounded to an even measurement quantity target chlorine concentration mgl 5. Water chlorination is the process of adding chlorine cl2 or hypochlorite to water. Chlorine can be added to water as a gas or in the form of hypochlorite either as liquid or solid. If a storage tank had 1 mg of water and it needed to be dosed with 11 mgl of gas chlorine, how many pounds of chlorine would this take. Techniques for chlorination of water supplies were developed in the late 19th and early 20th centuries.
Revised february 24, 2014 formulaconversion table for. Epa set the first regulatory limits for thms in 1979. The chlorine dose required depends on two considerations. Specific gravity is incorporated as part of the solution strength % wv. Therefore the formulas listed above 2,500 ppm are more than adequate. Sulfur dioxide is most commonly used for dechlorination and is the major focus of this fact.
Drinking water chlorination chlorine chemistry division. Although the pros and cons of disinfection with chlorine have been extensively debated,it remains the most widely used chemical for disinfection of water. Basic water treatment math formulas for surface and well. Table of contents executive summary chlorination and public health chlorine. Pdf chlorine is the most widely used disinfectant in egyptian drinking water because it is effective at low.
Water treatment math chlorine dose calculation youtube. Basic water and wastewater formulas p age of four tech brief basic water and wastewater formulas, winter 2008, vol. Measurement conversion measurement conversion measurement conversion measurement conversion 1 ft. Water chlorination learn how chlorination of water. Jan 20, 2018 learn how to calculate chlorine dose in this video, using the our five step process to solving math problems. Among other requirements, method 2 for disinfection of a water storage tank requires that a 200 mg per liter 200 mgl solution be brushed or sprayed on all surfaces that will come in contact with the potable water to be stored. If a new storage tank measured 40 ft in diameter and were 30 ft tall, how many. The equations for sodium hypochlorite solution strength preparation are based on mixing 12.
Controllingmonitoring chlorination of cooling water. Preflush water source prior to chlorination until water has chlorine residual less than 2. Drinking water chlorination world chlorine council position paper 2008 5 dbp formation can be reduced through costeffective methods, particularly by reducing the amount of natural organic material in water through filtrationor other means prior to disinfection. Among other requirements, method 2 for disinfection of a water storage tank requires that a 200 mg per liter 200 mgl solution be brushed or sprayed on all surfaces that will come in contact with the potable water. It is important to add sufficient chlorine to the water to meet the chlorine demand and provide residual disinfection. The most common chemical disinfectant for water treatment, and the one that has historically made the greatest contribution to the prevention of waterborne disease worldwide, is chlorine. Influence of flour chlorination and ingredient formulation on the quality attributes of pancakes s. This is used to disinfect water and make it safe for human use, such as for drinking water or swimming pools. Instrumentation since raw water can contain either free. The safe water system sws was developed in the 1990s in response to epidemic cholera in south america by the centers for disease control and prevention cdc and the pan american health organization paho. The centers for disease control recommends a bleach water ratio which produces at least 1,000 ppm sodium hypochlorite. Wcc supports adoption of these methods whenever possible. The disinfectant of choice the risks of waterborne disease the challenge of disinfection byproducts drinking water and security comparing alternative disinfection methods the future of chlorine disinfection glossary references. L along the interior of the pipe with a contact time of.
This technical brief describes a method of calculating the dose of chlorine required to disinfect small community water supplies. Even with the full range of benefits provided by the. The optimum chlorine residual in a small, communal water supply is in the range of 0. Basic water and wastewater formulas summary operators obtaining or maintaining their certification must be able to calculate complex formulas and conversion factors. When no source of water from existing main is available, provide potable water. Shock chlorination of a storage tank or reservoir consists of the following steps. The chlorine dose required to disinfect a supply will increase if the water is very turbid. This calculator can be used to adjust the chlorine concentration of water to disinfect it for drinking and also for other applications. Coli, which remains after chlorination has occurred. In particular, chlorination is used to prevent the spread of waterborne diseases such as cholera, dysentery, and typhoid. In this annexe we will show how the chlorine demand of water can be determined. The fundamentals of chlorine chemistry and disinfection. Influence of flour chlorination and ingredient formulation on.
Chlorination involves adding a measured amount of chlorine to water to produce a residual sufficient to kill bacteria, viruses, and cysts. Chlorine in drinkingwater world health organization. Chloramines combined chlorine if you smell chlorine, coming from your pool, what you really smell are combined forms of chlorine, also called chloramines. However, disinfection will not correct water problems caused by chemical contamination from nitrate, fuels, pesticides, or other substances. Cl2 dosage, mgl 9,525 x gallons of naocl solution injected x %naocl wv. Drinking water shock cholorination calculation sheet. The epa first published a water treatment manual on disinfection in 1998. Diluted household bleach solutions at least 1,000 ppm sodium hypochlorite can be used if appropriate for. Chlora stir well for 10 seconds, or until the hth has dissolved. Nov 27, 2016 the chlorination process involves adding chlorine to water, but the chlorinating product does not necessarily have to be pure chlorine. Tanks come in a variety sizes ranging from 750 l 165 gallons to over 50.
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